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The audio file for the adjective "cleanly" is the same as that for the adverb "cleanly".
However, the two words are not pronounced the same.
Auch die Stilebene ist offensichtlich eine andere: beim Adjektiv ist im lexico-Eintrag archaic vermerkt.
I see that Merriam-Webster doesn't mark the adjective as archaic; on the other hand, some online dictionaries don't seem to list it at all. I would say it's fairly rare nowadays in BE.
Has it an archaic ring to it when you hear "cleanly woman"?
Yes. Unlike the noun "cleanliness", which is in common use.